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Click on the son or daughter
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Click the "Change or delete" button
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Click "Change parents"
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Use the first two drop down boxes to pick the people who are already in the tree to be the parents
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Use the third dorpdown box to set what kind of parents they are.
This functionality is one of the most hidden features in the user interface. i wouldn't feel bad about not being able to find it. My suggestion was to make a parent's tab, like the Partners tab and put all of the parent related functionality there.